Conformations of propane Experiments show that there is a 14 kJ/mol (3.4 kcal/mol) barrier to rotation in propane.

The most stable (low energy) conformation is the one in which all of the bonds as far away from each other as possible ( staggered when viewed end-on in a Newman projection). Instead of analyzing both C-C bonds at the same time, it is more convenient to look at a single C-C and generalize the behavior of the remaining methyl group. Below are two representations of butane in a conformation which puts the two CH 3 groups (C 1 and C 4) in the eclipsed position. Conceptually, propane can be viewed as ethane with one methyl substituent. eclipsed conformation. steric repulsion (strain) In butane, there are three rotating carbon-carbon sigma bonds to consider, but we will focus on the middle bond between C 2 and C 3.

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